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Systems approach equilibrium over time from "summary" of Thermodynamics and an Introduction to Thermostatistics by Herbert B. Callen

The systems approach is a powerful tool for understanding the behavior of physical systems. In this approach, we consider a system and its surroundings as a whole, rather than focusing solely on the system itself. This allows us to take into account the interactions between the system and its environment, which can have a significant impact on the system's behavior. Equilibrium is a key concept in thermodynamics, and it plays a central role in the systems approach. When a system is in equilibrium, its properties do not change over time. This means that the system is in a stable state, with no net flow of energy or matter between the system and its surroundings. Over time, a system will tend towards equilibrium. This is because systems natura...
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    Thermodynamics and an Introduction to Thermostatistics

    Herbert B. Callen

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