Fluctuations affect macroscopic properties from "summary" of Thermodynamics and an Introduction to Thermostatistics by Herbert B. Callen
In the realm of thermodynamics, it is crucial to understand the intricate interplay between microscopic fluctuations and macroscopic properties. These fluctuations, arising from the random motion of particles on a microscopic scale, have significant implications on the behavior of systems at a macroscopic level. They can lead to variations in observable quantities such as pressure, volume, and temperature, thereby impacting the overall thermodynamic behavior of a system. At a fundamental level, fluctuations stem from the inherent randomness of particle motion in a system. This randomness gives rise to fluctuations in quantities such as energy and momentum, which in turn influence the overall thermodynamic properties of the system. While these fluctuations may seem insignificant on an individual basis, their cumulative effect can manifest in observable...
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