Transition state theory overview from "summary" of Physical Chemistry by Robert G. Mortimer
Transition state theory provides a framework for understanding the rates of chemical reactions. According to this theory, in order for a reaction to occur, the reactants must pass through a high-energy transitional state. This transitional state represents the maximum energy point along the reaction coordinate. The transition state theory also considers the activation energy, which is the energy barrier that must be overcome for the reaction to proceed.
The transition state theory is based on the concept of the activated complex, which is a temporary arrangement of atoms that exists at the transition state. The activated complex is highly unstable and short-lived, making it difficult to observe directly. However, its existence can be inferred from experimental data and theoretical cal...
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