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Coordination compounds have metal ions bonded to ligands from "summary" of NCERT Chemistry Class 11 - [CBSE Board] by Dr. S. C. Rastogi, ,Er. Meera Goyal

Coordination compounds are formed when metal ions are bonded to ligands. These compounds are made up of a central metal atom or ion that is bonded to a surrounding array of ions or molecules, known as ligands. The metal ion acts as a Lewis acid, while the ligands act as Lewis bases by donating a pair of electrons to the metal ion. Ligands can be classified as either monodentate, bidentate, or polydentate, depending on the number of donor atoms they contain. Monodentate ligands have a single donor atom, bidentate ligands have two donor atoms, and polydentate ligands have multiple donor atoms. The coordination number of a metal ion in a complex is determined by the number of bonds it forms with the ligands. The bond between the metal ion and the ligands in a coordination compound is known as a coordinate covalent bond. In this type of bond, both electrons of the shared pair come from the ligand, which acts as an electron pair donor. This results in the formation of a stable complex in which the metal ion is surrounded by ligands in a specific geometric arrangement. The coordination compounds exhibit various interesting properties due to the presence of metal-ligand bonds. These compounds often have distinct colors, show paramagnetism or diamagnetism, and can exhibit different reactivities compared to simple metal salts. The study of coordination compounds is crucial in understanding the behavior of transition metals in biological systems, catalysis, and materials science.
  1. The formation of coordination compounds involves the bonding of metal ions to ligands through coordinate covalent bonds, leading to the formation of stable complexes with unique properties and structures. This concept plays a significant role in various fields of chemistry and is essential for understanding the behavior of transition metals in different environments.
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NCERT Chemistry Class 11 - [CBSE Board]

Dr. S. C. Rastogi,

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